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Cocaine freed from impurites by treatment (usually with ether) by heating it to produce vapors for inhalation. When you create freebbase you [neutralize] the HCI, leaving you with pure cocaine. This is commonly confused with crack, which is typically 2 parts cocaine, 1 part [baking soda] and a little water heated gently to form crystals, which the user then smokes/inhales. Both are derived from cocaine and the effects are similar but [freebase] and crack are not created equal.
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