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Silver Cyanide is used in silver-plating. Its structure consist of -Ag-CN- chains in which the linear two-coordinate Ag+ ions are bridged by the cyanide ions, typical of silver(I) and other d10 ions . (This is the same binding mode as seen in the more famous case of [Prussian blue].) These chains then pack hexagonally with adjacent chains offset by +/- 1/3 of the "c" lattice parameter. This is the same as the structure adopted by the high [temperature] polymorph of copper(I) cyanide. The silver to carbon and silver to nitrogen bond lengths in AgCN are both ~2.09 Å and the cyanide groups show head-to-tail disorder. It has a crystal like, colorless, grey (impure) [appearance].
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