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A combination of the words “ Cope” and “Opium” (an addictive drug). It is a fictional gas that someone is said to be inhaling as a way to cope with an unfavourable situation. This is where the “Cope” comes from. The “Opium” part of this word is mostly for comedic effect however also implies that the person does this constantly as Opium is a very addictive drug. Inhaling Copium is a coping measure whereby someone rejects a harsh truth and instead adopts a less disturbing reality so they can feel better about their situation.
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